Search results for "Keto Acids"

showing 3 items of 3 documents

A detailed identification study on high-temperature degradation products of oleic and linoleic acid methyl esters by GC–MS and GC–FTIR

2012

GC-MS and GC-FTIR were complementarily applied to identify oxidation compounds formed under frying conditions in methyl oleate and linoleate heated at 180ºC. The study was focused on the compounds that originated through hydroperoxide scission that remain attached to the glyceridic backbone in fats and oils and form part of non-volatile molecules. Twenty one short-chain esterified compounds, consisting of 8 aldehydes, 3 methyl ketones, 4 primary alcohols, 5 alkanes and 1 furan, were identified. In addition, twenty non-esterified volatile compounds, consisting of alcohols, aldehydes and acids, were also identified as major non-esterified components. Furanoid compounds of 18 carbon atoms form…

030309 nutrition & dieteticsLinoleic acidMass-spectrometrychemistry.chemical_elementGas-chromatographyOleic AcidsBiochemistryGas Chromatography-Mass Spectrometry03 medical and health scienceschemistry.chemical_compound0404 agricultural biotechnologyFourier transform infraredFuranSpectroscopy Fourier Transform InfraredMoleculeOrganic chemistryMolecular BiologyBond cleavage0303 health sciencesAldehydesPrimary (chemistry)Organic ChemistryTemperaturePolar compounds04 agricultural and veterinary sciencesCell Biology040401 food scienceKeto AcidsThermoxidationShort-chain glycerol-bound compoundschemistryLinoleic AcidsGas chromatographyGas chromatography–mass spectrometryCarbon[SDV.AEN]Life Sciences [q-bio]/Food and Nutrition
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Double-blind cross-over study with oral alpha-ketoacids in patients with chronic renal failure.

1980

In 15 ambulatory patients with renal insufficiency (creatinine clearance, 9.9 +/- 3.0 ml/min) the effect of oral supplementation with alpha-ketoacids has been compared with that of placebo. The protein intake amounted to 0.55 g protein per kilogram body weight of high biological value, as estimated by dietary recordings. After a control period of 3 months the patients received, in a double-blind study, 1.05 g alpha-ketoacids/10 kg body weight per day or a placebo for 6 weeks with a subsequent cross-over. Fasting blood samples were analyzed at 3-week intervals for routine laboratory parameters and 17 proteins. Anthropometric and clinical data have been recorded every 3 weeks. While therapy w…

AdultMalemedicine.medical_specialtyMedicine (miscellaneous)Renal functionAlpha (ethology)PlaceboGastroenterologyPhosphatesPlacebosElectrolytesDouble-Blind MethodInternal medicinemedicineHumansClinical Trials as TopicNutrition and Dieteticsbusiness.industrynutritional and metabolic diseasesBiological valueBlood ProteinsAnthropometryMiddle AgedCrossover studyKeto AcidsDietClinical trialEndocrinologyCreatinineAmbulatoryKidney Failure ChronicFemalebusinessThe American journal of clinical nutrition
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Enzymatic and pharmacokinetic studies on the metabolism of branched chain alpha-keto acids in the rat.

1983

Michaelis-constants and enzyme activities for dehydrogenation and transamination of the three branched chain alpha-keto acids in liver, kidney, skeletal muscle, and brain of rats are reported. After oral load only 11-22% of the keto acids pass the liver unchanged. Blood levels in pharmacokinetic and absorption studies are related to the Michaelis-constants. At the low keto-acid concentrations after oral application, dehydrogenation in the non-hepatic tissues is supposed to prevail over transamination. Data on feed efficiency of branched chain alpha-keto acids reported in the literature support this view. The chance for transamination is better after intravenous administration. The transfera…

MaleStereochemistryTransaminationMedicine (miscellaneous)Mitochondria LiverKidneyBiochemistryHemiterpenesPharmacokineticsmedicineAnimalsDehydrogenationTransaminases3-methyl-2-oxobutyratechemistry.chemical_classificationKidneyCell-Free SystemSkeletal muscleBrainRats Inbred StrainsMetabolismKeto AcidsMitochondriaMitochondria MuscleRatsKineticsmedicine.anatomical_structureEnzymeBiochemistrychemistryOxidoreductasesFood ScienceZeitschrift fur Ernahrungswissenschaft
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